Methods of Forming Charge-Trapping Regions

ABSTRACT

Some embodiments include methods of forming charge-trapping zones. The methods may include forming nanoparticles, transferring the nanoparticles to a liquid to form a dispersion, forming an aerosol from the dispersion, and then directing the aerosol onto a substrate to form charge-trapping centers comprising the nanoparticles. The charge-trapping zones may be incorporated into flash memory cells.

TECHNICAL FIELD

Methods of forming charge-trapping regions.

BACKGROUND

Memory devices provide data storage for electronic systems. One type ofmemory is a non-volatile memory known as flash memory. A flash memory isa type of EEPROM (electrically-erasable programmable read-only memory)that may be erased and reprogrammed in blocks. Many modern personalcomputers have BIOS stored on a flash memory chip. Flash memory is alsopopular in wireless electronic devices because it enables themanufacturer to support new communication protocols as they becomestandardized, and to provide the ability to remotely upgrade the devicefor enhanced features.

A typical flash memory comprises a memory array that includes a largenumber of non-volatile memory cells arranged in row and column fashion.The cells are usually grouped into blocks. Each of the cells within ablock may be electrically programmed by charging a charge storageregion. The charge may be removed from the charge storage region by ablock erase operation. Data is stored in a cell as charge in the chargestorage region.

NAND is a basic architecture of flash memory. A NAND cell unit comprisesat least one select gate coupled in series to a serial combination ofmemory cells (with the serial combination being commonly referred to asa NAND string). The gates of the NAND string have traditionally beensingle level cells (SLCs), but manufacturers are transitioning toutilization of multilevel cells (MLCs) for gates of NAND strings. An SLCstores only one data bit, whereas an MLC stores multiple data bits.Accordingly, memory can be at least doubled by transitioning from SLCsto MLCs.

Charge has traditionally been stored within flash memory in a floatinggate. The floating gate may comprise, for example, conductively-dopedsilicon. Recently, interest has developed in utilizing charge-trappingmaterials to store charge. The charge-trapping materials may be layers(such as layers of silicon nitride) that have charge-trapping centerstherein, or may be discrete islands that individually function ascharge-trapping centers.

Of particular interest is the utilization of nanoparticles ascharge-trapping centers; with nanoparticles being understood to bestructures less than or equal to about 1000 nanometers along a maximalcross-section, and frequently less than 10 nanometers, or even less than3 nanometers along a cross-section. In some applications, thenanoparticles may have maximal cross-sectional dimensions of from about1 nanometer to about 100 nanometers. The nanoparticles may be configuredto trap less than or equal to about 20 charges, and may, for example, beconfigured to trap from about one charge to about 20 charges. Thenanoparticles may be substantially spherical, and the substantiallyspherical nanoparticles may be referred to as nanodots.

The nanoparticles may have any of numerous compositions, and may, forexample, comprise, consist essentially of, or consist of one or more ofAu, Ag, Co, Ge, Ir, Ni, Pd, Pt, Re, Ru, Si, Ta, Te, Ti and W.

The amount of charge stored on individual nanoparticles may depend onthe size and composition of the nanoparticles.

Problems with the utilization of nanoparticles occur in obtaininguniform distribution of nanoparticles (i.e., a uniform populationdensity of the nanoparticles as expressed in nanoparticles per unitarea), and uniform size of the nanoparticles. If there is too muchvariation in distribution and/or size of the nanoparticles, then theremay be excessive variation in cell-to-cell performance parameters.Variation in cell-to-cell performance may be particularly problematicfor MLC-type devices.

It is desired to develop fabrication processes which alleviate orovercome one or more of the above-discussed difficulties.

BRIEF DESCRIPTION OF THE DRAWINGS

FIG. 1 is a diagrammatic, cross-sectional view of a flash memory cellembodiment.

FIG. 2 is a flow-chart diagram of processes in accordance with someembodiments.

FIG. 3 is a diagrammatic, cross-sectional view of a structure which maybe utilized during the harvesting of nanoparticles in accordance with anembodiment.

FIG. 4 is a diagrammatic, cross-sectional view of a container containingnanoparticles.

FIG. 5 is a diagrammatic, cross-sectional view of a process for coatingnanoparticles in accordance with an embodiment.

FIG. 6 is a diagrammatic, cross-sectional view of a process for coatingnanoparticles in accordance with an embodiment.

FIGS. 7 and 8 are diagrammatic, cross-sectional views of coatednanoparticles in accordance with a couple of embodiments.

FIG. 9 is a diagrammatic, cross-sectional view of an apparatus forsorting nanoparticles by size.

FIG. 10 is a diagrammatic, cross-sectional view of an apparatus whichmay be utilized for distributing nanoparticles across a substrate.

FIGS. 11-14 illustrate process stages of an example embodiment methodfor fabricating a flash memory cell.

FIG. 15 is a diagrammatic view of a computer embodiment.

FIG. 16 is a block diagram showing particular features of themotherboard of the FIG. 15 computer embodiment.

FIG. 17 is a high level block diagram of an electronic systemembodiment.

FIG. 18 is a simplified block diagram of a memory device embodiment.

DETAILED DESCRIPTION OF THE ILLUSTRATED EMBODIMENTS

In some embodiments, the invention includes processes in whichnanoparticles are formed, cleaned and sorted by size to form a powder ofuniformly-sized nanoparticles. Such powder may then be dispersed withina liquid. Subsequently, an aerosol may be formed from the liquid havingthe nanoparticles dispersed therein, and such aerosol may be directedonto a substrate. The nanoparticles may form a distribution ofcharge-trapping centers across the substrate, and such distribution maybe incorporated into flash memory.

Example embodiments are described below with reference to FIGS. 1-18.

Referring to FIG. 1, an example embodiment of a flash memory cell 15 isshown as part of a semiconductor construction 10.

The semiconductor construction comprises a base 12. Base 12 may, forexample, comprise, consist essentially of, or consist of monocrystallinesilicon lightly-doped with background p-type dopant, and may be referredto as a semiconductor substrate, or as a portion of a semiconductorsubstrate. The terms “semiconductive substrate” and “semiconductorsubstrate” are defined to mean any construction comprisingsemiconductive material (for instance silicon and/or germanium),including, but not limited to, bulk semiconductive materials such as asemiconductive wafer (either alone or in assemblies comprising othermaterials thereon), and semiconductive material layers (either alone orin assemblies comprising other materials). The term “substrate” refersto any supporting structure, including, but not limited to, thesemiconductive substrates described above.

A gate stack 14 is supported by base 12. The gate stack includes atunnel dielectric 16, a charge-trapping zone 18 over the tunneldielectric, a blocking dielectric material 20 over the charge-trappingzone, and a control gate 22 over the blocking dielectric material.

The shown embodiment comprises a single charge-trapping zone 18 withinthe memory cell. Other embodiments may have additional charge-trappingzones stacked over the illustrated charge trapping zone of the memorycell.

The charge-trapping zone 18 comprises a plurality of discrete islands ofcharge-trapping material (the islands are labeled 19). The islands areillustrated to comprise electrically conductive material (such asmetal), but in other embodiments at least some of the islands maycomprise charge-trapping dielectric material. The islands may correspondto nanoparticles (such as, for example, nanodots) in some embodiments.The charge-trapping material may comprise metal, conductively-dopedsemiconductor material (for instance, conductively-doped silicon orgermanium) and/or silicon nitride.

In some embodiments, the charge-trapping islands may comprise, consistessentially of, or consist of one or more of Au, Ag, Co, Ge, Ir, Ni, Pd,Pt, Re, Ru, Si, Ta, Te, Ti and W.

The blocking dielectric material 20 may comprise any suitablecomposition or combination of compositions. In some embodiments, theblocking dielectric material 20 will comprise high-k dielectricmaterial. At least a portion of the high-k dielectric material may becharge-trapping material, such as silicon nitride; and the high-kdielectric material may thus supplement the charge-trappingcharacteristics of the charge-trapping zones. In other embodiments, theblocking dielectric material 20 will consist of dielectric material thatis not charge trapping; with such dielectric material being silicondioxide and/or high-k material. In some embodiments, the blockingdielectric material 20 will comprise one or more oxides selected fromthe group consisting of lanthanide oxides, HfSiON, HfO₂, Al₂O₃,HfAl_(x)O_(y), HfSi_(p)O_(q), and ZrO₂; where x, y, p and q are greaterthan zero.

The tunnel dielectric material 16 may comprise any suitable compositionor combination of compositions, and may, for example, comprise, consistessentially of, or consist of silicon dioxide and/or various high-kmaterials.

The control gate 22 may comprise any suitable composition or combinationof compositions. For instance, the control gate may comprise one or moreof various metals (for instance, tungsten, titanium, etc.),metal-containing compositions (for instance, metal silicides, metalnitride, etc.) and conductively-doped semiconductor materials (forinstance, conductively-doped silicon, etc.).

A pair of source/drain regions 24 are formed on opposing sides of gatestack 14. In the shown embodiment, the source/drain regions areconductively-doped regions of the semiconductor material of base 12.Regions 24 may be either n-type or p-type majority doped.

Some embodiments include methods of forming a flash memory cell, suchas, for example, the cell of FIG. 1. Example methods are particularlydirected toward procedures which may be utilized for formingnanoparticles 19 of uniform size, and composition; and toward procedureswhich may be utilized for forming uniform population densities ofnanoparticles across a plurality of memory cells (with populationdensity being the number of nanoparticles per unit area).

FIG. 2 shows a flow chart diagram of example processing that may be usedin some embodiments. An initial step 30 comprises making of thenanoparticles.

The next step (32) is to wash/dry the nanoparticles and form a powder ofthe nanoparticles. An arrow 31 designates process flow from step 30 tostep 32.

A subsequent step 34 is to deposit the nanoparticles onto a substrate toform charge-trapping centers. Such charge-trapping centers may then beincorporated into a flash memory cell in further processing (not shownin FIG. 2).

The processing from the powder formation of step 32 to the deposition ofnanoparticles of step 34 is linked by a dashed-line arrow 33. Thedashing of the line is used to indicate that such is one of a pluralityof alternate process flow paths. Another path is designated by adashed-line arrow 35 as proceeding to a step 36 of coating thenanoparticles, and then by a dashed-line arrow 37 indicating that thecoated nanoparticles may subsequently proceed to the step 34 ofdeposition of the nanoparticles. The coating of the nanoparticles maycomprise forming a dielectric shell around the nanoparticles (asdiscussed below with reference to FIG. 7), or forming a conductive shellaround the nanoparticles (as discussed below with reference to FIG. 8).

Additional processing which may occur during a process flow of FIG. 2 isthe sorting of the nanoparticles by size. Such sorting may occur aftermaking the nanoparticles and before washing and drying them (in otherwords, between steps 30 and 32); after washing and drying thenanoparticles and before depositing them (in other words, between steps32 and 34); after washing and drying the nanoparticles and beforecoating them (in other words, between steps 32 and 36); after coatingthe nanoparticles and before depositing them (in other words betweensteps 36 and 34); or during the deposition of the nanoparticles (inother words, during step 34). Example processes for sorting thenanoparticles are discussed below with reference to FIGS. 9 and 10.

The forming of the nanoparticles at step 30 of FIG. 2 may comprise anysuitable methodology, including, for example, sonochemistry as describedin an article by A. Nemamcha, et. al. (A. Nemamcha, et. al., Synthesisof Palladium Nanoparticles by Sonochemical Reduction of Palladium (II)Nitrate in Aqueous Solution, J. Phys. Chem. B. 2006, 110, 383-387), andelectrochemistry as described in U.S. Pat. No. 6,585,947 to Nayfeh et.al. The nanoparticles formed by sonochemistry or electrochemistry willbe formed in a first medium (specifically, the liquid carrier,electrolyte and/or electrodes utilized during the sonochemistry orelectrochemistry), and may be considered to be associated with the firstmedium. Another method is to form the nanoparticles across a supportingsurface utilizing conventional methods. The conventional methods mayinclude, for example, deposition of a thin film (specifically, a film ofthickness of from about 1 nanometer to about 1.2 nanometers) followed bye-beam evaporation; co-sputtering metal with embedding insulator; pulsednucleation; and/or templated self-assembly. Such conventionalmethodology may form constructions analogous to the construction 40 ofFIG. 3 comprising nanoparticles 19 supported on a substrate 42. Thenanoparticles 19 are supported by a first medium corresponding tosubstrate 42, and may be considered to be associated with such firstmedium.

Regardless of which method is utilized to form the nanoparticles, thenanoparticles are subsequently cleaned by washing them with one or moreappropriate solvents, and then drying them. The washing may includingfiltering the nanoparticles to separate them from liquid solutionsand/or cleaning materials. The cleaning of the nanoparticles may beconsidered to separate the nanoparticles from the first medium that hadbeen initially associated with the nanoparticles, regardless of whethersuch first medium is a liquid of a sonochemical method; an electrolyteor electrode of an electrochemical process; or a substrate of theconstruction of FIG. 3. If the nanoparticles are formed across asubstrate as shown in FIG. 3, the nanoparticles may be first strippedfrom over the substrate by, for example, dissolving the substrate and/orby mechanical agitation of the substrate and/or by mechanical brushingof the nanoparticles.

The washing of the nanoparticles may comprise utilization of one or morevolatile solvents, such as, for example, one or more of isopropylalcohol, water, methanol and ethanol. The drying may be conducted atroom temperature, or at a temperature higher than room temperature, andmay be conducted during agitation of the nanoparticles to enablecomplete removal of the solvent.

After the nanoparticles are washed and dried, they form a powder whichmay be retained within a vessel, as illustrated in FIG. 4. Specifically,FIG. 4 shows a vessel 44 retaining a powder comprising a plurality ofnanoparticles 19 (only some of which are labeled).

In some embodiments, the nanoparticles may be subsequently coated toform a shell or coating encapsulating the nanoparticles. FIGS. 5 and 6illustrate example methods that may be utilized for coating thenanoparticles.

Referring to FIG. 5, a vessel 46 is shown retaining a fluid 48. Thenanoparticles 19 (only some of which are labeled) are shown being pouredfrom the container 44 and into the fluid 48. The fluid may be ofappropriate viscosity to coat the nanoparticles, and may be ofappropriate composition that it may be cured to form a substantiallysolid coating around the nanoparticles. For instance, the fluid maycomprise a sol-gel suspension, and the curing of the fluid may form anoxide (for instance silicon dioxide) encapsulating the nanoparticles.After the nanoparticles are poured into the fluid, they may be removedfrom vessel 46, strained to remove excess fluid, and then subjected toappropriate conditions to cure the material remaining around thenanoparticles (such material may be referred to as a coating precursor)to thereby form encapsulating shells (or coatings) around the individualnanoparticles.

FIG. 6 illustrates an alternative method of forming encapsulating shellsaround the nanoparticles. Specifically, FIG. 6 illustrates a chamber 50suitable for physical vapor deposition (PVD), atomic layer deposition(ALD) and/or chemical vapor deposition (CVD). Nanoparticles 19 areplaced within the chamber, and then exposed to material 52 whichdeposits an encapsulating shell (not shown in FIG. 6) around thenanoparticles. The deposition may comprise PVD, ALD or CVD.

Yet another method of forming a coating, when the coating iselectrically conductive, is to plate the coating onto the nanoparticles.The plate may comprise electrolytic plating or electroless platingmethodology.

FIGS. 7 and 8 illustrate encapsulated nanoparticles. FIG. 7 shows ananoparticle 19 encapsulated with dielectric material 54, and FIG. 8shows a nanoparticle 19 encapsulated with conductive material 56.

The dielectric material of FIG. 7 may comprise silicon dioxide and/orhigh-k material. In some embodiments, the dielectric material will benon-charge-trapping; and in other embodiments the dielectric materialwill be charge-trapping (for instance, the dielectric material mayconsist of silicon nitride). The dielectric material may be formed toany desired thickness, and may, for example, be formed to a thickness offrom about 10 angstroms to about 100 angstroms. The dielectric materialmay have an electrically neutral outer surface, or may have a chargedouter surface. For instance, the dielectric material outer surface maycomprise carboxyl groups to provide a negative charge along the outersurface, or may comprise amino groups to provide a positive charge alongthe outer surface.

The electrically conductive material 56 of FIG. 8 may comprise elementalmetal, and/or may comprise one or more metal-containing compounds (forinstance, metal nitride, metal silicide, etc.), and/or may compriseconductively-doped semiconductor material. The electrically conductivematerial 56 may be formed to any desired thickness, and may, forexample, be formed to a thickness of from about 10 angstroms to about100 angstroms.

As discussed above with reference to FIG. 2, the nanoparticles may besize sorted at any of numerous processing stages. An example apparatusthat may be utilized for size sorting is diagrammatically illustrated inFIG. 9 as an apparatus 60. Such apparatus comprises an inlet chute 62which leads to a sorting mechanism 64, and further comprises outletstreams 66 and 68 exiting the sorting mechanism. The sorting mechanismmay comprise, for example, a plurality of screens, anelectrostatic-based differential mobility analyzer, a time of flightanalyzer, and/or a magnetic deflection analyzer. The outlet streams 66and 68 correspond to two different populations of nanoparticles sortedby size (with one of the populations shown as a population 67 of smallernanoparticles, and the other shown as a population 69 of largernanoparticles). Within each population, the nanoparticles may be thesame size to within 10 percent (by volume), and accordingly may bewithin the same size to within from about 0.1 nanometers to about onenanometer. In some embodiments, the sorted nanoparticles may be nanodotshaving diameters of from about 2 nanometers to about 5 nanometers.Although only two populations are shown, in other embodiments more thantwo populations may be separated from one another by the sortingapparatus.

The powdered nanoparticles of FIG. 4, coated nanoparticles of FIGS. 7and 8, and/or sorted nanoparticles of FIG. 9 may be distributed across asubstrate utilizing any suitable method. An example method that may beparticularly suitable for forming a uniform population density of thenanoparticles across a substrate is to utilize an aerosol-generatingapparatus. Specifically, the nanoparticles are initially dispersedwithin a carrier fluid to form a dispersion, and subsequently suchdispersion is passed through an aerosol-generating apparatus to form anaerosol which is directed toward a substrate surface. The nanoparticleswithin the aerosol are uniformly distributed across the substratesurface as they are carried by the aerosol to the substrate surface. Thecarrier fluid may comprise one or more volatile solvents (for instance,isopropyl alcohol, water, ethanol, methanol, etc.) so that the carrierfluid may be evaporated after the nanoparticles have been distributedacross the surface.

An example aerosol-generating apparatus 70 is diagrammaticallyillustrated in FIG. 10. The apparatus 70 includes a sidewall 72 thatextends around a reaction chamber 74. Ports 76 extend through thesidewall to the chamber, and valves 78 regulate flow of materialsthrough the ports. In operation, the valves may be utilized to controlflow of gas into and out of the chamber so that desired pressure may beprovided within the chamber. One or more of the ports may be in fluidcommunication with a pump (not shown), which may be utilized duringcontrol of the pressure within the chamber.

A substrate holder 80 is within the chamber, and such retains asubstrate 82. The substrate holder may be configured to retain specifictypes of substrates. In some embodiments, the substrate 82 maycorrespond to a semiconductor substrate, and the substrate holder may beconfigured to retain the semiconductor substrate (for instance, thesubstrate holder may have a recess with a size and shape complementaryto the semiconductor substrate).

An aerosol-forming nozzle 84 is within the chamber, and in fluidconnection with a reservoir 86. In operation, liquid (specifically, thedispersion of nanoparticles in carrier liquid) is passed from reservoir86 and through nozzle 84, whereupon it is atomized. The atomized liquidis then dispersed into the chamber as liquid aerosol particles(diagrammatically illustrated as aerosol particles 88, only some ofwhich are labeled). The aerosol-forming nozzle may be comprised by anysuitable aerosol generator, and may, for example, correspond to anelectrostatic nozzle, a piezoelectric nozzle, an ultrasonic or megasonicnozzle, or an electrohydrodynamic atomization nozzle.

Although nozzle 84 is shown within chamber 74, in other embodiments thenozzle may be external of the chamber so that aerosol is formed outsideof the chamber, and then passed through an opening in the chambersidewall to enter the chamber. In any event, nozzle 84 will be proximatethe chamber so that aerosol formed by the nozzle may be directed towardthe upper surface of the substrate 82 retained within the chamber.

The aerosol particles 88 are directed toward an upper surface ofsubstrate 82. Such may be accomplished by fluid-force propulsion throughnozzle 84. The propulsion of the aerosol particles toward the substratesurface may alternatively, or additionally, include blending a gas jetwith the fluid stream entering nozzle 84, and utilizing the gas streamto push the aerosol particles toward the substrate. In some embodiments,the propulsion of the aerosol particles toward the substrate surface mayalternatively, or additionally, include providing electrical charge tothe aerosol particles and to one or more components within the chamberso that the aerosol particles may be electrostatically attracted and/orrepelled from various components to direct the aerosol particles towardthe substrate. For instance, focusing rings and/or electrodes (notshown) may be utilized to direct the aerosol particles.

In the shown embodiment, nozzle 84 is coupled with a power source 90.The nozzle 84 may be an electrohydrodynamic nozzle powered by source 90.Further, the power source 90 may be utilized to induce a polarity to theaerosol particles 88. In some embodiments, a polarity may be induced onsubstrate 82 which is opposite to that induced on aerosol particles 88(for instance, the polarity on the aerosol particles may be negative andthat induced on the upper surface of substrate may be positive). Theopposite polarities may cause the aerosol particles 88 to be attractedto the upper surface of the substrate by electrostatic forces.

The aerosol particles 88 are shown covering only a small region of theupper surface of substrate 82. In some embodiments, it may be desired toprovide the nanoparticles on only specific small regions of the uppersurface of the substrate. In other embodiments, it may be desired toprovide the nanoparticles across an entirety of the upper surface of thesubstrate. If it is desired to provide the nanoparticles across theentirety of the upper surface of the substrate, multiple nozzles may beused to create aerosol coverage across the entire surface.Alternatively, or additionally, one or both of the substrate and theaerosol-generating nozzle may be moved during treatment of thesubstrate. For instance, substrate holder 80 is shown connected to amotor 92 which in turn is connected with a power source 94. The motormay be configured to rotate the substrate holder (as illustrated byarrow 93) when powered by the source 94. The rotation of the substrateholder rotates substrate 82. Rotation of substrate 82 may enable moreuniform dispersal of the nanoparticles across an upper source of thesubstrate than would be achieved without rotation. Also, nozzle 84 isshown coupled to a motor 96, which in turn is coupled to a powersource/control unit 98. The motor 96 may be utilized for moving thenozzle 84 laterally within the chamber (as illustrated by arrows 95 and97) which, in combination with rotation of substrate 82, may enable thenozzle to be utilized for dispersal of nanoparticles across the entiresurface of substrate 82.

Although all of the aerosol is shown directed toward the substrate, inpractice the aerosol may disperse within the chamber so that some of theaerosol particles do not reach the substrate surface. In someembodiments, the aerosol-generating apparatus is utilized to size sortthe nanoparticles. Specifically, the aerosol droplets containingnanoparticles of appropriate size are directed toward the substrate,while aerosol droplets containing nanoparticles outside of a desiredsize range are not directed along trajectories that reach a surface ofthe substrate.

An example process for utilizing nanoparticle distribution of the typedescribed in FIG. 10 for fabrication of flash memory cells is describedwith reference to FIGS. 11-14. Identical numbering will be used indescribing FIGS. 11-14 as is used above in describing FIG. 1.

Referring to FIG. 11, construction 10 is shown at an initial processingstage. The construction comprises substrate 12 and the tunnel dielectric16 formed over substrate 12.

Referring to FIG. 12, nanoparticles 19 are uniformly distributed acrossan upper surface of tunnel dielectric 16. Such uniform distribution isaccomplished utilizing an aerosol generator, such as the example aerosolgenerator of FIG. 10. The carrier liquid discussed with reference toFIG. 10 has been volatilized to leave only nanoparticles 19 across theupper surface of tunnel dielectric 16. In the shown embodiment, thenanoparticles are not coated. In other embodiments, the nanoparticles atthe processing stage of FIG. 12 may correspond to the coatednanoparticles of FIG. 7 or FIG. 8.

The nanoparticles 19 shown in FIG. 12 are of uniform size relative toone another as may be accomplished utilizing the sorting apparatus ofFIG. 9 and/or utilizing size sorting with the aerosol generator asdiscussed with reference to FIG. 10. The individual nanoparticles 19 arespaced from one another by intervening gaps.

Referring to FIG. 13, blocking dielectric material 20 is deposited overnanoparticles 19, and within the gaps between the nanoparticles. Also,control gate material 22 is deposited over the blocking dielectricmaterial 20.

Referring to FIG. 14, the materials 16, 20 and 22 are patterned to formthe gate stack 14, and source/drain regions 24 are formed adjacent thegate stack by implanting appropriate dopant into substrate 12.

The nanoparticles 19 form charge-trapping centers within gate stack 14.The amount of charge stored by such charge-trapping centers, and theease with which the charge may be transferred to and from thecharge-trapping centers, may be influenced by the type of materialsutilized for nanoparticles 19, the size of the nanoparticles, and thepopulation density of the nanoparticles.

Flash memory cells formed in accordance with the embodiments discussedabove may be incorporated into electronic systems, such as, for example,computer systems, cars, phones, cameras, planes, etc.

FIG. 15 illustrates an embodiment of a computer system 400. Computersystem 400 includes a monitor 401 or other communication output device,a keyboard 402 or other communication input device, and a motherboard404. Motherboard 404 may carry a microprocessor 406 or other dataprocessing unit, and at least one memory device 408. Memory device 408may comprise an array of memory cells, and such array may be coupledwith addressing circuitry for accessing individual memory cells in thearray. Further, the memory cell array may be coupled to a read circuitfor reading data from the memory cells. The addressing and readcircuitry may be utilized for conveying information between memorydevice 408 and processor 406. Such is illustrated in the block diagramof the motherboard 404 shown in FIG. 16. In such block diagram, theaddressing circuitry is illustrated as 410 and the read circuitry isillustrated as 412.

Processor device 406 may correspond to a processor module, andassociated memory utilized with the module may comprise flashstructures.

Memory device 408 may correspond to a memory module, and may compriseflash memory.

FIG. 17 illustrates a simplified block diagram of a high-levelorganization of an electronic system 700. System 700 may correspond to,for example, a computer system, a process control system, or any othersystem that employs a processor and associated memory. Electronic system700 has functional elements, including a processor 702, a control unit704, a memory device unit 706 and an input/output (I/O) device 708 (itis to be understood that the system may have a plurality of processors,control units, memory device units and/or I/O devices in variousembodiments). Generally, electronic system 700 will have a native set ofinstructions that specify operations to be performed on data by theprocessor 702 and other interactions between the processor 702, thememory device unit 706 and the I/O device 708. The control unit 704coordinates all operations of the processor 702, the memory device 706and the I/O device 708 by continuously cycling through a set ofoperations that cause instructions to be fetched from the memory device706 and executed. The memory device 706 may include flash memory, suchas a flash card.

FIG. 18 is a simplified block diagram of an electronic system 800. Thesystem 800 includes a memory device 802 that has an array of memorycells 804, address decoder 806, row access circuitry 808, column accesscircuitry 810, read/write control circuitry 812 for controllingoperations, and input/output circuitry 814. The memory device 802further includes power circuitry 816, and sensors 820, such as currentsensors for determining whether a memory cell is in a low-thresholdconducting state or in a high-threshold non-conducting state. Theillustrated power circuitry 816 includes power supply circuitry 880,circuitry 882 for providing a reference voltage, circuitry 884 forproviding a first wordline with pulses, circuitry 886 for providing asecond wordline with pulses, and circuitry 888 for providing a bitlinewith pulses. The system 800 also includes a processor 822, or memorycontroller for memory accessing.

The memory device 802 receives control signals from the processor 822over wiring or metallization lines. The memory device 802 is used tostore data which is accessed via I/O lines. At least one of theprocessor 822 or memory device 802 may include flash memory.

The various electronic systems may be fabricated in single-packageprocessing units, or even on a single semiconductor chip, in order toreduce the communication time between the processor and the memorydevice(s).

The electronic systems may be used in memory modules, device drivers,power modules, communication modems, processor modules, andapplication-specific modules, and may include multilayer, multichipmodules.

The electronic systems may be any of a broad range of systems, such asclocks, televisions, cell phones, personal computers, automobiles,industrial control systems, aircraft, etc.

In compliance with the statute, the subject matter disclosed herein hasbeen described in language more or less specific as to structural andmethodical features. It is to be understood, however, that the claimsare not limited to the specific features shown and described, since themeans herein disclosed comprise example embodiments. The claims are thusto be afforded full scope as literally worded, and to be appropriatelyinterpreted in accordance with the doctrine of equivalents.

1. A method of forming a charge-trapping zone, comprising: forming aplurality of nanoparticles; transferring the nanoparticles to a liquid,and forming a dispersion of the nanoparticles within the liquid; formingan aerosol from the dispersion; and directing the aerosol onto asubstrate to form charge-trapping centers comprising the nanoparticles,individual charge-trapping centers being spaced from one another byintervening gaps.
 2. The method of claim 1 wherein the nanoparticles aremetallic.
 3. The method of claim 1 wherein the nanoparticles consist ofelemental metal.
 4. The method of claim 1 further comprising coating thenanoparticles with dielectric material prior to transferring thenanoparticles to the liquid, and wherein the coated nanoparticles aredirected by the aerosol onto the substrate.
 5. The method of claim 4wherein the dielectric material comprises silicon dioxide.
 6. The methodof claim 4 wherein the dielectric material comprises silicon nitride. 7.The method of claim 4 wherein the coating utilizes one or more ofphysical vapor deposition, chemical vapor deposition and atomic layerdeposition.
 8. The method of claim 4 wherein the coating utilizes a dipof the nanoparticles within a fluid to form coating precursor around thenanoparticles, followed by a cure of the coating precursor to form thecoated nanoparticles.
 9. The method of claim 4 wherein the dielectricmaterial forms charged surfaces around the coated nanoparticles.
 10. Themethod of claim 9 wherein the charged surfaces comprise carboxyl groups.11. The method of claim 9 wherein the charged surfaces comprise aminogroups.
 12. The method of claim 1 further comprising coating thenanoparticles with electrically conductive material prior totransferring the nanoparticles to the liquid, and wherein the coatednanoparticles are directed by the aerosol onto the substrate.
 13. Themethod of claim 12 wherein the electrically conductive materialcomprises elemental metal.
 14. The method of claim 12 wherein theelectrically conductive material comprises a metal-containing compound.15. The method of claim 12 wherein the coating utilizes one or more ofphysical vapor deposition, chemical vapor deposition, atomic layerdeposition and plating.
 16. A method of forming a charge-trapping zone,comprising: forming a plurality of nanoparticles over a surface;stripping the nanoparticles from the surfaces; cleaning thenanoparticles; transferring the cleaned nanoparticles to a liquid, andforming a dispersion of the nanoparticles within the liquid; forming anaerosol from the dispersion; and directing the aerosol onto a substrateto form charge-trapping centers comprising the nanoparticles, individualcharge-trapping centers being spaced from one another by interveninggaps.
 17. The method of claim 16 further comprising sorting thenanoparticles by size prior to forming the aerosol.
 18. The method ofclaim 16 further comprising sorting the nanoparticles by size during thedirecting of the aerosol onto the substrate.
 19. The method of claim 16wherein the forming the aerosol comprises utilization of anelectrostatic nozzle, a piezoelectric nozzle, an ultrasonic nozzle, oran electrohydrodynamic atomization nozzle.
 20. The method of claim 16wherein the nanoparticles are metallic.
 21. The method of claim 16further comprising coating the nanoparticles with dielectric materialprior to transferring the nanoparticles to the liquid, and wherein thecoated nanoparticles are directed by the aerosol onto the substrate. 22.The method of claim 21 wherein the dielectric material forms chargedsurfaces around the coated nanoparticles.
 23. The method of claim 16further comprising coating the nanoparticles with electricallyconductive material prior to transferring the nanoparticles to theliquid, and wherein the coated nanoparticles are directed by the aerosolonto the substrate.
 24. The method of claim 23 wherein the electricallyconductive material comprises elemental metal.
 25. The method of claim23 wherein the electrically conductive material comprises ametal-containing compound.
 26. A method of forming a charge-trappingzone, comprising: forming a plurality of nanoparticles associated with afirst medium; separating the nanoparticles from the first medium andforming a powder of the nanoparticles; dispersing of the powder within aliquid to form a dispersion; forming an aerosol from the dispersion; anddirecting the aerosol onto a substrate to form charge-trapping centerscomprising the nanoparticles, individual charge-trapping centers beingspaced from one another by intervening gaps.
 27. The method of claim 26further comprising sorting the nanoparticles by size prior to formingthe powder.
 28. The method of claim 26 further comprising sorting thenanoparticles by size after forming the powder and prior to forming theaerosol.
 29. The method of claim 26 further comprising sorting thenanoparticles by size during the directing of the aerosol onto thesubstrate.
 30. The method of claim 26 wherein the nanoparticles aremetallic.
 31. The method of claim 30 further comprising coating thenanoparticles with dielectric material prior to transferring thenanoparticles to the liquid, and wherein the coated nanoparticles aredirected by the aerosol onto the substrate.
 32. The method of claim 31wherein the dielectric material forms charged surfaces around the coatednanoparticles.
 33. The method of claim 30 further comprising coating thenanoparticles with electrically conductive material prior totransferring the nanoparticles to the liquid, and wherein the coatednanoparticles are directed by the aerosol onto the substrate.
 34. Themethod of claim 33 wherein the electrically conductive materialcomprises elemental metal.
 35. The method of claim 33 wherein theelectrically conductive material comprises a metal nitride.